Product Name: Chlorotrimethylsilane
Synonyms: CHLOROTRIMETHYLSILANE, 98+%CHLOROTRIMETHYLSILANE, 98+%CHLOROTRIMETHYLSILANE, 98+%;CHLOROTRIMETHYLSILANE GC 99+%;Trimethylchlorosilane, 98+%;TMSchloride;CHLOROTRIMETHYLSILANE (TRIMETHYLCHLOROSILANE);Chlorotrimethylsilane, 1M solution in dichloromethane;Chlorotrimethylsilane, 1M solution in tetrahydrofuran;CHLOROTRIMETHYLSILANE, 98+%
CAS: 75-77-4
MF: C3H9ClSi
MW: 108.64206
EINECS: 200-900-5
Product Categories: Pharmaceutical Intermediates;Chloro;Organics;Analytical Chemistry;Biochemistry;GC Derivatizing Reagents;Monochlorosilanes;Nucleosides, Nucleotides & Related Reagents;Protecting Agents for Hydroxyl and Amino Groups;Protecting Agents, Phosphorylating Agents & Condensing Agents;Protection & Derivatization Reagents (for Synthesis);Reagents for Oligosaccharide Synthesis;Si (Classes of Silicon Compounds);Si-Cl Compounds;Silicon Compounds (for Synthesis);Silylation (GC Derivatizing Reagents);Synthetic Organic Chemistry;Trimethylsilylation (GC Derivatizing Reagents);Blocking Agents;Chloro Silanes;Protective Agents;Silylating Agents;Silylation Reagents;Silicone Series;organosilicon compounds
Mol File: 75-77-4.mol
Chlorotrimethylsilane Structure
Chlorotrimethylsilane Chemical Properties
Melting point −40 °C(lit.)
Boiling point 57 °C(lit.)
density 0.857 g/mL at 25 °C
vapor density 3.7 (vs air)
vapor pressure 100 mm Hg ( 25 °C)
refractive index n20/D 1.500
Fp 104 °F
storage temp. Store at RT.
solubility Miscible with ether, benzene, diethylether and perchloroethylene.
form Liquid
Specific Gravity 0.8536 (27℃)
color Clear colorless
explosive limit 1.5-46%(V)
Water Solubility REACTS
Hydrolytic Sensitivity 8: reacts rapidly with moisture, water, protic solvents
Sensitive Moisture Sensitive
BRN 1209232
Stability: Stable. Highly flammable - note low flash point. Reacts violently with water. Incompatible with water, moisture, strong oxidizing agents, strong acids, strong bases, aldehydes, alcohols, amines, esters, ketones.
InChIKey IJOOHPMOJXWVHK-UHFFFAOYSA-N
CAS DataBase Reference 75-77-4(CAS DataBase Reference)
NIST Chemistry Reference Silane, chlorotrimethyl-(75-77-4)
EPA Substance Registry System Trimethylchlorosilane (75-77-4)
Safety Information
Hazard Codes T,F,C,Xn
Risk Statements 20/21-36/38-34-21-14-11-37-35-19-40-10-67-20/21/22-52
Safety Statements 26-36/37/39-45-16-36/37-7/9
RIDADR UN 2924 3/PG 2
WGK Germany 2
RTECS VV2710000
F 10-21
Autoignition Temperature 752 °F
Hazard Note Highly Flammable/Corrosive/Moisture Sensitive
TSCA Yes
HazardClass 3
PackingGroup II
HS Code 29310095