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tert-Butanol Basic information
Product Name: tert-Butanol
Synonyms: 2-Methyl n-propan-2-ol;2-methyl-2-propano;2-Methylpropanol-[2];2-Methylpropanol-2;2-Propanol, 2-methyl-;2-propanol,2-methyl-;Alcool butylique tertiaire;alcoolbutyliquetertiaire
CAS: 75-65-0
MF: C4H10O
MW: 74.12
EINECS: 200-751-6
Product Categories: Organics;ACS and Reagent Grade Solvents;Carbon Steel Flex-Spout Cans;Plastic Bottles;ReagentPlus;ReagentPlus Solvent Grade Products;Semi-Bulk Solvents;Solvent Bottles;Solvent by Application;Solvent Packaging Options;Solvents;Anhydrous Solvents;Sure/Seal Bottles;Analytical Reagents;Analytical Reagents for General Use;Analytical/Chromatography;Histological Solvents;Puriss p.a. ACS;T-Z
Mol File: 75-65-0.mol
tert-Butanol Structure
tert-Butanol Chemical Properties
mp  23-26 °C(lit.)
bp  83 °C(lit.)
density  0.81 g/mL at 25 °C(lit.)
vapor density  2.55 (vs air)
vapor pressure  31 mm Hg ( 20 °C)
refractive index  n20/D 1.399(lit.)
Fp  95 °F
storage temp.  2-8°C
Water Solubility  soluble
Merck  14,1542
BRN  906698
Stability: Stable. Very flammable. Incompatible with strong oxidizing agents, copper, copper alloys, alkali metals, aluminium.
CAS DataBase Reference 75-65-0(CAS DataBase Reference)
NIST Chemistry Reference Ethanol, 1,1-dimethyl-(75-65-0)
EPA Substance Registry System 2-Propanol, 2-methyl-(75-65-0)
Safety Information
Hazard Codes  Xn,F,T
Risk Statements  11-20-39/23/24/25-23/24/25-36/37
Safety Statements  9-16-45-36/37-7-46-26
RIDADR  UN 1120 3/PG 3
WGK Germany  1
RTECS  EO1925000
HazardClass  3
PackingGroup  II
HS Code  29051410
Hazardous Substances Data 75-65-0(Hazardous Substances Data)
MSDS Information
Provider Language
tert-Butanol English
SigmaAldrich English
ACROS English
ALFA English
tert-Butanol Usage And Synthesis
Chemical Properties clear colourless liquid after melting
General Description Colorless oily liquid with a sharp alcohol odor. Floats and mixes with water. Produces irritating vapor. Freezing point is 78°F.
Air & Water Reactions Highly flammable. Water soluble.
Reactivity Profile Attacks plastics. [Handling Chemicals Safely 1980. p. 236]. Acetyl bromide reacts violently with alcohols or water [Merck 11th ed. 1989]. Mixtures of alcohols with concentrated sulfuric acid and strong hydrogen peroxide can cause explosions. Example: an explosion will occur if dimethylbenzylcarbinol is added to 90% hydrogen peroxide then acidified with concentrated sulfuric acid. Mixtures of ethyl alcohol with concentrated hydrogen peroxide form powerful explosives. Mixtures of hydrogen peroxide and 1-phenylm-2-methyl propyl alcohol tend to explode if acidified with 70% sulfuric acid [Chem. Eng. News 45(43):73 1967; J, Org. Chem. 28:1893 1963]. Alkyl hypochlorites are violently explosive. They are readily obtained by reacting hypochlorous acid and alcohols either in aqueous solution or mixed aqueous-carbon tetrachloride solutions. Chlorine plus alcohols would similarly yield alkyl hypochlorites. They decompose in the cold and explode on exposure to sunlight or heat. Tertiary hypochlorites are less unstable than secondary or primary hypochlorites [NFPA 491 M 1991]. Base-catalysed reactions of isocyanates with alcohols should be carried out in inert solvents. Such reactions in the absence of solvents often occur with explosive violence [Wischmeyer 1969].
Health Hazard Vapor is narcotic in action and irritating to respiratory passages. Liquid is irritating to skin and eyes.
Fire Hazard tert-Butanol is flammable.
tert-Butanol Preparation Products And Raw materials
Raw materials Etanol-->Benzene-->ISOBUTYLENE-->1,3-BUTADIENE-->SULFATE STANDARD-->Liquefied petroleum ges-->Sodium tert-butoxide
Preparation Products ETHOPERMETHRIN，95%-->(R,R)-(+)-HYDROBENZOIN-->(2-TERT-BUTOXYFORMAMIDO-PYRIDIN-4-YL)METHYL METHANESULFONATE-->5-Bromo-7-azaindole-->(2-BROMO-PYRIDIN-3-YL)-CARBAMIC ACID TERT-BUTYL ESTER-->TERT-BUTYL GLYCIDYL ETHER-->4-TERT-BUTYL-2,6-DIMETHYL BENZYL ACETATE-->tert-Butyl peroxybenzoate-->tert-Butyl acetate -->2,4-Dichlorophenoxybutyric acid-->5-TERT-BUTYL-M-XYLENE-->Dibutyl sebacate-->Di-tert-butyl peroxide-->tert-Butyl peroxypivalate -->TERT-BUTYL ISOTHIOCYANATE-->4-ALLYL-PIPERIDINE-1,4-DICARBOXYLIC ACID MONO-TERT-BUTYL ESTER-->1-CHLORO-4-ISOCYANOBENZENE-->TERT-BUTYL 4-(HYDROXYMETHYL)PYRIDIN-2-YLCARBAMATE-->Butoconazole-->6-tert-Butyl-m-cresol-->2,4-DI-(TERT-BUTOXY)-5-BROMOPYRIMIDINE-->2-tert-Butyl-4,5-dichloro-3-2H-pyridazinone-->tert-Butyl peroxy-2-ethylhexanoate-->Butylparaben-->4-Tert-butyl-2,6-dimethylbenzylchloroide -->2-tert-Butyl-4-methylphenol-->5-TERT-BUTOXYCARBONYLAMINO-PYRIDINE-3-CARBOXYLIC ACID-->sodium butyl 9(or 10)-(sulphonatooxy)octadecanoate -->4-(BROMOMETHYL)-BENZOIC ACID, 1,1-DIMETHYLETHYL ESTER-->4-PIPERIDINECARBOXYLIC ACID T-BUTYL ESTER HCL-->RH-5849(Rhom & Haas-->Butyl stearate -->Dispersant CS-->2,2'-Methylenebis(6-tert-butyl-4-methylphenol)-->TERT-BUTYL 4-(METHOXYCARBONYL)PYRIDIN-2-YLCARBAMATE-->3-CHLORO-2-HYDROXY-5-(TRIFLUOROMETHYL)PYRIDINE