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Product Name: Methylcyclohexane
Synonyms: Cyclohexane,methyl-;Cyclohxylmethane;heptanaphthene;hexahydrodoluene;hexahydro-toluen;Hexahydroxytoluene;methyl-cyclohexan;methylecyclohexane
CAS: 108-87-2
MF: C7H14
MW: 98.19
EINECS: 203-624-3
Product Categories: cyclic compounds;Analytical Chemistry;Solvents for HPLC & Spectrophotometry;Solvents for Spectrophotometry;HPLC Solvents;ACS and Reagent Grade Solvents;Amber Glass Bottles;Carbon Steel Cans with NPT Threads;ReagentPlus;ReagentPlus Solvent Grade Products;Semi-Bulk Solvents;Solvent Bottles;Solvent by Application;Solvent Packaging Options;Solvents;Anhydrous Solvents
Mol File: 108-87-2.mol
Methylcyclohexane Structure
Methylcyclohexane Chemical Properties
mp  -126.3 °C
bp  101 °C(lit.)
density  0.77 g/mL at 25 °C(lit.)
vapor density  3.4 (vs air)
vapor pressure  37 mm Hg ( 20 °C)
refractive index  n20/D 1.422(lit.)
Fp  25 °F
storage temp.  Flammables area
Water Solubility  0.1 g/L (20 ºC)
Merck  14,6047
BRN  505972
Stability: Stable. Very flammable. Incompatible with strong oxidizing agents.
CAS DataBase Reference 108-87-2(CAS DataBase Reference)
NIST Chemistry Reference Cyclohexane, methyl-(108-87-2)
EPA Substance Registry System Cyclohexane, methyl-(108-87-2)
Safety Information
Hazard Codes  F,Xn,N
Risk Statements  11-38-51/53-65-67
Safety Statements  9-16-33-61-62
RIDADR  UN 2296 3/PG 2
WGK Germany  2
RTECS  GV6125000
F  3-10
HazardClass  3
PackingGroup  II
Hazardous Substances Data 108-87-2(Hazardous Substances Data)
MSDS Information
Provider Language
Hexahydrotoluene English
SigmaAldrich English
ACROS English
ALFA English
Methylcyclohexane Usage And Synthesis
Chemical Properties colourless liquid
General Description A clear colorless liquid with a petroleum-like odor. Flash point 25°F. Less dense than water and insoluble in water. Vapors heavier than air.
Air & Water Reactions Highly flammable. Insoluble in water.
Reactivity Profile Saturated aliphatic hydrocarbons, such as Methylcyclohexane, may be incompatible with strong oxidizing agents like nitric acid. Charring of the hydrocarbon may occur followed by ignition of unreacted hydrocarbon and other nearby combustibles. In other settings, aliphatic saturated hydrocarbons are mostly unreactive. They are not affected by aqueous solutions of acids, alkalis, most oxidizing agents, and most reducing agents.
Health Hazard Harmful if inhaled or swallowed. Vapor or mist is irritating to the eyes, mucous membrane and upper respiratory tract and skin. Narcotic effects and dermititis.
Fire Hazard Special Hazards of Combustion Products: Vapor may travel considerable distance to a source of ignition and flashback containing explosion may occur during fire conditions. Forms explosive mixtures in air.
Methylcyclohexane Preparation Products And Raw materials
Raw materials Dehydrolyzing agent
Preparation Products Heptane-->Ethacrynic acid-->2,5-DIMETHYL-1,3-OXAZOLE-4-CARBALDEHYDE-->(2,5-DIMETHYL-1,3-OXAZOL-4-YL)METHANOL-->5-BROMO-2-FLUOROPHENYLACETIC ACID-->ADS-->2,2-DIMETHYL-N-PYRIDIN-4-YL-PROPIONAMIDE-->trans-1,4-Diaminocyclohexane