Product Name: Triethylsilane
Synonyms: TRIETHYLSILANE, 97%TRIETHYLSILANE, 97%TRIETHYLSILANE, 97%;Triethylsilyl;Triethylsilane,99%;Silane, triethyl-;Triethylsilane, 98.5+%;Triethylsilicon;Triethylsilane,Triethylsilyl hydride;Triethylsilane ,97%
CAS: 617-86-7
MF: C6H16Si
MW: 116.28
EINECS: 210-535-3
Product Categories: Other Reagents;Reduction;Si (Classes of Silicon Compounds);Si-H Compounds;Silicon Compounds (for Synthesis);Synthetic Organic Chemistry;Alkyl Silanes;Hydrogensilanes Hydrogensiloxanes;Reducing Agents;Chemistry;Silanes;Synthetic Reagents;organosilicon compound;1;Organics
Mol File: 617-86-7.mol

Triethylsilane Chemical Properties
Melting point  -157°C
Boiling point  107-108 °C(lit.)
density  0.728 g/mL at 25 °C(lit.)
vapor pressure  >1 hPa (20 °C)
refractive index  n20/D 1.412(lit.)
Fp  25 °F
storage temp.  2-8°C
form  liquid
color  colorless
Specific Gravity 0.728
Water Solubility  Miscible with water.
Sensitive  Moisture Sensitive
Hydrolytic Sensitivity 3: reacts with aqueous base
BRN  1098278
Stability: Stable, but moisture sensitive. Highly flammable. Generates highly flammable gas (hydrogen) in contact with water, acids and bases.
CAS DataBase Reference 617-86-7(CAS DataBase Reference)
NIST Chemistry Reference Silane, triethyl-(617-86-7)
EPA Substance Registry System Triethylsilane (617-86-7)
Safety Information
Hazard Codes  F,Xi
Risk Statements  11-36/37/38-52/53
Safety Statements  9-16-29-33-37/39-26-61
RIDADR  UN 1993 3/PG 2
WGK Germany  1
F  10-21
TSCA  Yes
HazardClass  3
PackingGroup  II
HS Code  29310095

Triethylsilane Usage And Synthesis
Referrence Triethylsilane is a useful versatile reductant since it has a active hydride. It can be used for mediated the palladium-catalyzed dehalogenation reaction of alkyl or aryl halides, the reduction of primary, secondary, and tertiary chlorides, bromides, and iodides catalyzed by iridium, as well as efficient reduction of multiple bonds, azides, imines, and nitro groups, as well as benzyl group and allyl group deprotection. It is also specifically for the hydrosilation of olefins to give alkyl silanes. It is also the catalyst for synthesis of a spiro-oxindole blocker of Nav1.7 for the treatment of pain, redox initiated cationic polymerization and Beckmann rearrangement of cyclododecanone oxime as well as regioselective reductive coupling of enones and allenes.

Product Name: Triethylsilane
Synonyms: TRIETHYLSILANE, 97%TRIETHYLSILANE, 97%TRIETHYLSILANE, 97%;Triethylsilyl;Triethylsilane,99%;Silane, triethyl-;Triethylsilane, 98.5+%;Triethylsilicon;Triethylsilane,Triethylsilyl hydride;Triethylsilane ,97%
CAS: 617-86-7
MF: C6H16Si
MW: 116.28
EINECS: 210-535-3
Product Categories: Other Reagents;Reduction;Si (Classes of Silicon Compounds);Si-H Compounds;Silicon Compounds (for Synthesis);Synthetic Organic Chemistry;Alkyl Silanes;Hydrogensilanes Hydrogensiloxanes;Reducing Agents;Chemistry;Silanes;Synthetic Reagents;organosilicon compound;1;Organics
Mol File: 617-86-7.mol

Triethylsilane Chemical Properties
Melting point  -157°C
Boiling point  107-108 °C(lit.)
density  0.728 g/mL at 25 °C(lit.)
vapor pressure  >1 hPa (20 °C)
refractive index  n20/D 1.412(lit.)
Fp  25 °F
storage temp.  2-8°C
form  liquid
color  colorless
Specific Gravity 0.728
Water Solubility  Miscible with water.
Sensitive  Moisture Sensitive
Hydrolytic Sensitivity 3: reacts with aqueous base
BRN  1098278
Stability: Stable, but moisture sensitive. Highly flammable. Generates highly flammable gas (hydrogen) in contact with water, acids and bases.
CAS DataBase Reference 617-86-7(CAS DataBase Reference)
NIST Chemistry Reference Silane, triethyl-(617-86-7)
EPA Substance Registry System Triethylsilane (617-86-7)
Safety Information
Hazard Codes  F,Xi
Risk Statements  11-36/37/38-52/53
Safety Statements  9-16-29-33-37/39-26-61
RIDADR  UN 1993 3/PG 2
WGK Germany  1
F  10-21
TSCA  Yes
HazardClass  3
PackingGroup  II
HS Code  29310095

Triethylsilane Usage And Synthesis
Referrence Triethylsilane is a useful versatile reductant since it has a active hydride. It can be used for mediated the palladium-catalyzed dehalogenation reaction of alkyl or aryl halides, the reduction of primary, secondary, and tertiary chlorides, bromides, and iodides catalyzed by iridium, as well as efficient reduction of multiple bonds, azides, imines, and nitro groups, as well as benzyl group and allyl group deprotection. It is also specifically for the hydrosilation of olefins to give alkyl silanes. It is also the catalyst for synthesis of a spiro-oxindole blocker of Nav1.7 for the treatment of pain, redox initiated cationic polymerization and Beckmann rearrangement of cyclododecanone oxime as well as regioselective reductive coupling of enones and allenes.